House Magazine Spring 2000

What exactly is a "dry hydrate"?

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What exactly is a dry hydrate? I had to wait nearly 25 years to fully understand the answer to that question, until a fine day in July 1999 when Gerard Lynch and Douglas Johnson built a small kiln in the top car park at the Museum, burnt some chalk overnight, and the very next day produced - a dry hydrate! It was a truly exciting moment, the feeling that after such a long wait the pieces had finally fallen into place.

Museum research director Richard Harris discovered during recent developments in demonstrating lime production at the Museum.

Lime has for many years been a watchword of the building conservation movement. As an architecture student in the early 1970s I had learned about modern cement-lime-sand mortar mixes, but by 1974 I needed to research traditional lime mortars for stonework being built at Avoncroft Museum of Buildings. At that time the main battle was to get builders to follow specifications and incorporate lime with cement and sand, as a market survey in 1969 had revealed that cement-sand mortars, with no additives at all, were being used on a large scale in Britain. Lime was almost always bought in bags from builders’ merchants, the bags containing a white powder, the so-called "dry hydrate" of lime.

 

Put in the simplest terms, lime is made by burning limestone (in our case, chalk). The quicklime thus produced is then slaked with water to form lime. This process is often expressed in terms of the so-called "lime cycle", because after the lime is used as mortar or plaster it "carbonates", taking in carbon dioxide from the air, and eventually reverts to a chemical form which is the same as the original limestone, calcium carbonate. The simple chemical reaction formulae are an easy way to remember the sequence.

lime article the lime cycle

 

So what is the "hydrate"? In the lime cycle, it is the product of slaking: calcium hydroxide. The important point to remember is that the hydrate can be either dry or wet, depending on how much water is used for slaking. If only just enough water is used, the hydrate will be dry, but if an excess of water is used, the hydrate will be a putty - or, with the addition of even more water, limewash.

Returning to the mid-1970s, at that time most of the written advice about lime came from government or commercial sources and it dealt almost entirely with the use of hydrated lime -- the dry powder bought in bags - as a constituent of cement-lime-sand mortars, A favourite (and typical) publication of the time was Lime in Building, by the charmingly named British Quarrying and Slag Federation; all its recommendations were for cement-lime-sand mixes, and it says: "Lime putty is rarely made nowadays on site from quicklime but is generally produced from hydrated lime. This is done by the gradual addition of hydrated lime to water ... to form a paste". However, various individuals were beginning to research lime in depth and rediscovering techniques for slaking lime from quicklime. For instance, a contemporary of mine at the Architectural Association, Mike Wingate, wrote a thesis on lime and went on to be a leading contributor to the field, including writing a book Small Scale Lime Burning (1985).

Another leading light was John Ashurst. His expertise and practical experience in the Ancient Monuments and Historic Buildings Directorate made him very influential, and through his teaching and writing he produced the classic Mortars, Plasters and Renders in Conservation (1983), and then in 1988 the magisterial English Heritage Technical Handbooks Practical Building Conservation. Here at last was the advice we needed. We were to forget about bagged hydrated lime and go back to basics, buying quicklime and slaking it. "Summary of procedures to obtain optimum performance from mortars based on non-hydraulic lime. 1. Slake freshly burnt lime on site with enough water to obtain a soft mass of putty. Continue stirring during the slaking process. Sieve to remove lumps. Keep the putty under a water layer for at least one week to ensure thorough slaking".

Inspired by this, we persuaded John Ashurst to come to the Museum to give us a "lime day" in January 1985, to try to improve our techniques. We had been using lime-only mortars (no cement) for 10 years, mainly with bagged hydrated lime, but not with complete success. Gradually our techniques improved. We built lime pits for slaking, and by the time we built Longport Farmhouse in 1994 we were confident in slaking and using lime. The mortar in Longport has certainly worked extremely well.

But then, two years ago, Gerard Lynch dropped a small bombshell into the cosy world of lime putty, in the form of a paper about lime mortars in the Journal of Architectural Conservation (March and July 1998). Gerard had served an apprenticeship as a bricklayer and became a master of his craft. He was one of the few people to know, and more importantly, to care about, the secrets of gauged brickwork - that is, brickwork using bricks that are cut and rubbed to very precise dimensions and laid with very thin joints. In 1990 he published his first book, Gauged Brickwork, then in 1994 Brickwork : history, technology and practice which established his reputation as one of the leading historians of architectural brickwork. I first met him in 1991 when I asked his advice on the Museum’s exhibition on Bricks and Brickwork (in the Petersfield brick drying shed). In 1993 he started running courses at the Museum and is now one of our most popular tutors.

In his paper Gerard argued that the conservation world’s focus on lime putty had made us forget the fact that historically most mortar for brickwork had been prepared in a quite different way. One of the most telling parts of his argument was that using lime pits for putty for mortar would simply not have been able to keep up with demand on busy sites. Twenty Georgian bricklayers building a terrace of houses, for instance, would need about 7 tons of slaked lime every day, which would require huge pits, worked on a rota. Lime certainly was slaked to putty in pits, but the product, the finest slaked lime available, was used mainly by plasterers.

So how was the mortar for general brickwork made? The answer lay in Gerard’s own experience as an apprentice, when he learned the techniques. The quicklime would arrive fresh and still warm from the kilns - or even be burnt on site - in the form of stones, which were broken up as small as possible. A "banker", or mixing platform, was formed from close-set wooden planks, and on it was placed a large ring of sand, perhaps a yard across. The quicklime (called "stone lime") was put in the middle of the sand and lightly watered, which would start it immediately slaking, the stone lumps beginning to spit, pop and crumble. Immediately, the ring of sand was drawn over to cover the lime: the dampness in the sand acts as a reservoir of moisture for slaking and helps to prevent "overburning" which damages the lime. Slaking generates heat, and steam would rise gently from the pile. After a while, when the slaking was judged to be complete, the pile was broken and mixed, and the result - if everything had been judged correctly - was a fine and intimate mixture of dry hydrate of lime and sand, the heat of slaking having helped it to dry.

The next step was to "screen" the dry mixture. This was done by using a shovel to cast or "punch" it at an inclined wire screen with a mesh of perhaps a quarter of an inch, thus screening out larger lumps, most of which would have been the underburnt "cores" of lumps of lime, which would not slake. After screening, the dry mixture would be knocked up with water, mixed with a "larry" - a sort of hoe with holes in the blade - and then was ready for use as required.

When I read Gerard’s paper I immediately felt that it had the "ring of truth", and it solved so many problems. Of course, it had all been there in the older textbooks, but we just hadn’t seen or understood it. Richard Neve, in The City and Country Purchaser (1703), says: "The best way ... is to take the sand and throw it on the lime whilst it is in the stones before it is run, and so mix it together, and then wet it. ... When you slack the lime you must take care to wet it everywhere a little (but not overwet it) and cover with sand every laying or bed of lime as you slack it, so that the spirit of the lime may be kept in and ... mix itself with the sand".

Excited and intrigued by Gerard’s paper (which also contains some important arguments about other aspects of lime) I offered him the opportunity to run a day school at the Museum to explain and demonstrate his ideas. He enthusiastically agreed, and enlisted the help of his friend Douglas Johnson, of Mason’s Mortars, Edinburgh, a leading lime expert and practitioner.

 

What happened next, however, took us all by surprise. Douglas and Gerard arrived at the Museum the afternoon before the course and Douglas, seeing that the Museum sits on chalk, immediately suggested that we burn some to make our own lime. No kiln? No problem -- we’ll build one, and a couple of hours later a small brick kiln had been built, just big enough to burn several buckets-full of chalk. Coal was borrowed from Whittaker’s Cottages, and the kiln was loaded and lit. It smoked, then built up to a full red heat (probably reaching a temperature of around 1000 degrees centigrade) and carried on burning through the night. Next morning our excited inspection revealed that the chalk had indeed burnt well: we had quicklime, and it slaked beautifully.

By late morning the lectures were over and, all agog, we went up to the kiln and emptied out the quicklime. Gerard demonstrated how to make the ring of sand, put the stone lime in the middle, water it, cover it, leave it - and an hour or so later he broke the pile to reveal exactly what he had predicted, a dry hydrate of lime intimately mixed with sand. This was screened, knocked up with water, and larried. Gerard was thrilled with the result, a really high quality mortar. Mick and Ron Betsworth rated it the best mortar they had ever used. It would improve if left for a day or two but was usable immediately - from chalk to mortar in 24 hours! What is more, its appearance fully matched that of historic lime mortars, which mortars made with lime putty never quite manage to do.

This pioneering test burn (and others we did subsequently) have opened up a whole new set of possibilities for us. We sit on chalk, and are just about to excavate many tons of it for the new Gridshell building. We know that it makes excellent lime. At the very least we will run regular demonstrations of small-scale lime burning (the next one will be at The Fire Event on 26 March). But should we perhaps build a larger kiln and produce Singleton lime, in the form of a dry hydrate ready mixed with sand? Semi-industrial processes producing products for sale bring their own problems, but it is a possibility and it would be a unique product. Certainly it would accord well with our belief that traditional processes and products, if properly understood, still have a place in modern life.

lime article punching or screening

Finally Gerard Lynch is "punching" the sand and dry hydrate through the screen.

 

 

 

 

 

 

 

 

 

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lime article the demonstration lime kiln

The demonstration kiln

lime article chalk after firing

After firing these lumps of chalk are now quicklime

lime article watering quicklime

Gerard Lynch watering the quicklime in the middle of the sand ring

lime article adding sand

The sand is pulled over the slaking lime.

lime article slaking lime

Feel the heat coming from the slaking pile.

 

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